Канал: Dr. B. Mohammed Nawaz

Zero order rate equation: Derivation.

Zero order rate equation: Derivation.

Third order rate equation: Derivation

Third order rate equation: Derivation

Second order rate equation: Derivation

Second order rate equation: Derivation

Flash photolysis: A study of fast reactions.

Flash photolysis: A study of fast reactions.

Stopped flow method of studying kinetics of fast reactions.

Stopped flow method of studying kinetics of fast reactions.

Kinetics of fast reactions:Relaxation method by temperature jump and pressure jump techniques.

Kinetics of fast reactions:Relaxation method by temperature jump and pressure jump techniques.

Rice-Herzfield mechanism for the decomposition of Acetaldehyde following one and halforder kinetics.

Rice-Herzfield mechanism for the decomposition of Acetaldehyde following one and halforder kinetics.

Rice-Herzfield mechanism for the decomposition of Acetaldehyde following half order kinetics.

Rice-Herzfield mechanism for the decomposition of Acetaldehyde following half order kinetics.

Rice-Herzfield mechanism for decomposition of organic compounds. First order kinetics.

Rice-Herzfield mechanism for decomposition of organic compounds. First order kinetics.

Explosion limits, Upper and lower explosion limits

Explosion limits, Upper and lower explosion limits

Linear chain and branching chain reactions.

Linear chain and branching chain reactions.

Chain reactions, General treatment of a chain reactions.

Chain reactions, General treatment of a chain reactions.

Parallel reactions kinetics study

Parallel reactions kinetics study

Consecutive reactions kinetic studies

Consecutive reactions kinetic studies

Kinetics of reversible reactions.

Kinetics of reversible reactions.

Determination of activity and activity coefficient of non electrolyte by vapour pressure measurement

Determination of activity and activity coefficient of non electrolyte by vapour pressure measurement

Choice of standard state of gases and solvent.

Choice of standard state of gases and solvent.

Concept of activity and activity coefficient in solutions, it's significance and free energy change

Concept of activity and activity coefficient in solutions, it's significance and free energy change

Determination of excess volume and excess enthalpy.

Determination of excess volume and excess enthalpy.

Excess functions. Excess chemical potential, free energy, Volume, enthalpy and entropy.

Excess functions. Excess chemical potential, free energy, Volume, enthalpy and entropy.

Importance of PH in living system, Derivation of Henderson's equation.

Importance of PH in living system, Derivation of Henderson's equation.

Thermodynamics of real gas and solutions, Vapour pressure curves of real solutions with +ve, -ve.

Thermodynamics of real gas and solutions, Vapour pressure curves of real solutions with +ve, -ve.

Buffer solution and buffer action

Buffer solution and buffer action

PH and it's determination by indicator method

PH and it's determination by indicator method

Electrochemical corrosion and it's prevention.

Electrochemical corrosion and it's prevention.

Conductometric titrations, Hcl Vs NaOH and CH3COOH Vs NaOH.

Conductometric titrations, Hcl Vs NaOH and CH3COOH Vs NaOH.

Kohlrausch's law, Determination of equivalent conductance of weak electrolyte (Acetic acid).

Kohlrausch's law, Determination of equivalent conductance of weak electrolyte (Acetic acid).

Specific, equivalent conductance and their determination, Effect of dilution.

Specific, equivalent conductance and their determination, Effect of dilution.

Determination of fugacity in gas mixtures, Lewis Randall rule

Determination of fugacity in gas mixtures, Lewis Randall rule

Variation of fugacity with temperature and pressure.

Variation of fugacity with temperature and pressure.

Concept and definition of fugacity, Determination of fugacity of a real gas.

Concept and definition of fugacity, Determination of fugacity of a real gas.

Variation of chemical potential with temperature and pressure.

Variation of chemical potential with temperature and pressure.

Determination of partial molar properties.

Determination of partial molar properties.

Chemical potential of mixture of gases and significance of partial molar properties.

Chemical potential of mixture of gases and significance of partial molar properties.

partial molar properties, Chemical potential, Gibbs Duhem equation.

partial molar properties, Chemical potential, Gibbs Duhem equation.

Irreversible Thermodynamics, Force, Flux, linear force flux relationship Phenomenological equations.

Irreversible Thermodynamics, Force, Flux, linear force flux relationship Phenomenological equations.

Radiation laws (Planck's, Stefan Boltzmann, Weins and Rayleigh Jeans), Electron gas in metals

Radiation laws (Planck's, Stefan Boltzmann, Weins and Rayleigh Jeans), Electron gas in metals

Fluorescence, Phosphorescence and Chemiluminescence

Fluorescence, Phosphorescence and Chemiluminescence

Photosensitisation and Photosynthesis

Photosensitisation and Photosynthesis

Photochemistry: Grothus Draper's law, Stark Einstein's Law and Quantum yield.

Photochemistry: Grothus Draper's law, Stark Einstein's Law and Quantum yield.

Distinction between homogenous and heterogeneous catalysis, Industrial applications of catalysts.

Distinction between homogenous and heterogeneous catalysis, Industrial applications of catalysts.

Catalyst, autocatalyst, promoter, enzyme catalyst, active center, poisoning.

Catalyst, autocatalyst, promoter, enzyme catalyst, active center, poisoning.

Nernst Equation derivation, Sign convention of electrode

Nernst Equation derivation, Sign convention of electrode

Electrode potential, Standard electrode potential and reference electrode

Electrode potential, Standard electrode potential and reference electrode

Glass electrode , electrode reactions.

Glass electrode , electrode reactions.

Half life period, Determination of rate constant of ester hydrolysis

Half life period, Determination of rate constant of ester hydrolysis

Order and molecularity differences, First order rate equation Allied Chemistry,Unit-III,B.Md.Nawaz

Order and molecularity differences, First order rate equation Allied Chemistry,Unit-III,B.Md.Nawaz

Comparison of Maxwell Boltzmann, Fermi Dirac and Bose Einstein statistics.

Comparison of Maxwell Boltzmann, Fermi Dirac and Bose Einstein statistics.

Types of electrodes. Gas, metal-metal ion, metal ion salt and redox electode.

Types of electrodes. Gas, metal-metal ion, metal ion salt and redox electode.

Bose-Einstein statistics

Bose-Einstein statistics

Fermi Dirac statistics.

Fermi Dirac statistics.

Reversible and irreversible cell, standard cell, measurement of emf.

Reversible and irreversible cell, standard cell, measurement of emf.

Ortho and para hydrogen

Ortho and para hydrogen

Activity and activity coefficient of electrolytes, Galvanic cell

Activity and activity coefficient of electrolytes, Galvanic cell

Debye's heat capacity of solids.

Debye's heat capacity of solids.

Wien effect, Debye Falkenhagen effect and Ionic strength

Wien effect, Debye Falkenhagen effect and Ionic strength

Nuclear partition function, Einstein's heat capacity of solids.

Nuclear partition function, Einstein's heat capacity of solids.

Debye Huckel theory of strong electrolytes and it's Verification.

Debye Huckel theory of strong electrolytes and it's Verification.

Application of partition function to the heat capacity of ideal gases.

Application of partition function to the heat capacity of ideal gases.

Conductometric Titrations.

Conductometric Titrations.

Determination of degree of dissociation, Determination of solubility of a sparingly soluble salt.

Determination of degree of dissociation, Determination of solubility of a sparingly soluble salt.

Buffer solution and it's applications

Buffer solution and it's applications

Thermodynamic functions in terms of partition function

Thermodynamic functions in terms of partition function

Hydrolysis of salt of week base and strong acid and hydrolysis of salt of week acid and week base

Hydrolysis of salt of week base and strong acid and hydrolysis of salt of week acid and week base

Vibrational partition function

Vibrational partition function

Hydrolysis of salt, PH of a solution and degree of hydrolysis.

Hydrolysis of salt, PH of a solution and degree of hydrolysis.

Rotational partition function

Rotational partition function

Kohlrausch's law and its applications

Kohlrausch's law and its applications

Partition function, Translational partition function

Partition function, Translational partition function

Transport number by moving boundary method effect of Temp and conc on ionic mobility and conductance

Transport number by moving boundary method effect of Temp and conc on ionic mobility and conductance

Maxwell Boltzmann distribution law and statistics.

Maxwell Boltzmann distribution law and statistics.

Variation of specific and equivalent conductance with dilution Transport number by Hittorf's method

Variation of specific and equivalent conductance with dilution Transport number by Hittorf's method

Statistical thermodynamics probability distribution distinguishable and indistinguishable particles

Statistical thermodynamics probability distribution distinguishable and indistinguishable particles

Metallic and Electrolytic conductors, specific, equivalent and molar conductance.

Metallic and Electrolytic conductors, specific, equivalent and molar conductance.

Electrokinetic phenomena, Membrane potential.

Electrokinetic phenomena, Membrane potential.

Fick's Law of diffusion, effect of ionic association on conductance.

Fick's Law of diffusion, effect of ionic association on conductance.

Zeta potential and its applications

Zeta potential and its applications

Two component system with incongruent point (Na-K) system.

Two component system with incongruent point (Na-K) system.

Ferric chloride- water system

Ferric chloride- water system

Stern model of electrical double layer

Stern model of electrical double layer

Freezing mixtures, Two component system compound formation with congruent point Zn-Mg system

Freezing mixtures, Two component system compound formation with congruent point Zn-Mg system

Guoy Chapmann theory of electrical double layer

Guoy Chapmann theory of electrical double layer

Reduced phase rule, Two component simple eutectic (Silver-Lead) system.

Reduced phase rule, Two component simple eutectic (Silver-Lead) system.

Sulphur system

Sulphur system

Helmholtz Perin model of electrical double layer

Helmholtz Perin model of electrical double layer

One component system, water system.

One component system, water system.

Gibbs phase rule, statement and definition of terms.

Gibbs phase rule, statement and definition of terms.

Electrocapillary phenomena, Lippmann equation

Electrocapillary phenomena, Lippmann equation

Solubility of partially miscible liquids, phenol water system, effect of impurity on CST

Solubility of partially miscible liquids, phenol water system, effect of impurity on CST

Electrode electrolyte interface and adsorption at interface.

Electrode electrolyte interface and adsorption at interface.

Distillation of immiscible liquids. Steam distillation.

Distillation of immiscible liquids. Steam distillation.

Azeotropic mixtures, Azeotropic distillation.

Azeotropic mixtures, Azeotropic distillation.

Qualitative and quantitative verification of Debye Huckel limiting law, Huckel and Onsager equation

Qualitative and quantitative verification of Debye Huckel limiting law, Huckel and Onsager equation

Fractional distillation

Fractional distillation

Debye Huckel limiting Law

Debye Huckel limiting Law

Thermodynamics of real solutions. The vap pr composition and BPcomposition curves of binary liquids.

Thermodynamics of real solutions. The vap pr composition and BPcomposition curves of binary liquids.

Activity coefficient of strong electrolyte, determination of activ coeff by electrochemical method

Activity coefficient of strong electrolyte, determination of activ coeff by electrochemical method

Debye Huckel theory of strong electrolytes, it's significance and verification

Debye Huckel theory of strong electrolytes, it's significance and verification

Thermodynamics of ideal solution. Free energy change, volume change and enthalpy change on mixing.

Thermodynamics of ideal solution. Free energy change, volume change and enthalpy change on mixing.

Ionic strength and calculations

Ionic strength and calculations

Activity component of ideal solution and GibbsDuhem Margulus equation

Activity component of ideal solution and GibbsDuhem Margulus equation

Mean ionic activity and activity coefficient

Mean ionic activity and activity coefficient

Henry's law, Raoult's law, Vapour pressure of binary solution.

Henry's law, Raoult's law, Vapour pressure of binary solution.

UGC NET/SET CHEMICAL SCIENCE PART II

UGC NET/SET CHEMICAL SCIENCE PART II

CSIR UGC NET/SET ( CHEMICAL SCIENCE)

CSIR UGC NET/SET ( CHEMICAL SCIENCE)

Nernst Equation

Nernst Equation

Sodium potassium ( incongruent) system

Sodium potassium ( incongruent) system

Ferric Chloride Water System (part II)

Ferric Chloride Water System (part II)

Ferric Chloride Water system (Part I)

Ferric Chloride Water system (Part I)