The following video shows how to obtain the pyromancy Chaos Storm in Dark Souls.
You will have to reach rank 2 in the Chaos Servant covenant.
So after killing Chaos Witch Quelaag head to Quelaag's Domain and talk to the White Spider. Join the covenant and to increase to rank 2 you will have to offer 30 humanities.
Once you have offered 30 humanities you will be rewarded with the pyromancy.
Dark Souls Remastered [Chaos Storm]
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