Iron supplements do not need a time, it needs the presence of vitamin C. Any iron supplement cannot be absorbed by the body until and unless there is a backup of vitamin C in the body. A lot of research has proved this. And honestly iron being a heavy metal you cannot be taking it early in the morning. Best time to take iron supplement would be to take it in the middle of the day and ensure that there is enough vitamin C in your diet in the day. It could be in the form of orange juice, sweet lemon juice, whatever you think. If none of it please also take a vitamin C supplement to supplement the absorption of iron through the system.
Best time of the day to take iron supplements - Dr. Surekha Tiwari
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