Carbs turn into sugar. And over time, too much sugar in the diet and fueling leads to a physiological addiction. This is hormonally driven and, yes, insulin is a heavy hitter, but this is a complex interplay of other hormones like leptin, ghrelin, your thyroid hormones and sex hormones all trying to compensate for the excess glucose flooding your bloodstream on a chronic basis.
From the OFM episode, "Are You In A Sugar Trap? Essential Truths for Athletes"
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