When the Shinigami begin to lose their respective battles and the Arrancar begin to mount a comeback that culminates in Aizen's escape, the Visored appear on the battlefield. Shinji briefly greets Aizen in a mocking manner, and then asks his fellow Visored if there is anyone in the Gotei 13 they would like to speak to. He ends up in a short argument with Hiyori, followed by the others expressing their disinterest in speaking to their former comrades, with the exception of Lisa, who flash steps away. Shinji then approaches Yamamoto to greet him, to which the commander asks if he has come for revenge. Shinji plainly tells him against Aizen, yes, but that he holds no such ambitions against the Gotei 13. Yamamoto asks Shinji if he is right to assume they are then allies, to which Shinji replies that they aren't. However, he clarifies that although they are not on the Gotei 13's side, they are against Aizen and are allies of Ichigo. He then returns to the other Visored, who bring forth their masks when Hooleer spews forth a huge amount of Gillian class Menos from its mouth. They then attack the Gillian, showing off each of their powers. Shinji, however, confronts Aizen and tells him it is time to finish this off. Before his attack can reach, Kaname Tōsen slashes at Shinji before the latter starts fighting Gin Ichimaru. Mashiro is defeated by Wonderweiss Margela, who then battles Kensei, only to later leave the fight to attack Yamamoto, leaving Kensei's fate unknown. Hachi sacrifices one of his arms to defeat Baraggan and cannot use his powers to his fullest, and Hiyori is bifurcated by Gin after being enraged by one of Aizen's taunts. Later, after Ichigo's return from Hueco Mundo, Shinji, Rose, Love and Lisa engage Aizen to protect Ichigo from his Shikai. Aizen effortlessly cuts down Rose, Love and Lisa. Shinji, along with Shunsui Kyōraku, Suì-Fēng, and Tōshirō Hitsugaya, mistakenly think that they have finally killed Aizen, but it turns out to be an illusion that tricked them into stabbing Momo Hinamori. When Shinji and the others try to stop an enraged Hitsugaya from charging at Aizen, the latter tells them that they're all wide open and defeats all of them with one slash each, sending Shinji and his comrades falling into the town. With that, the only Visored still able to battle is Ichigo.
