The largest of Pluto's five moons, Charon, was discovered on June 22, 1978, by James Christy and Robert Harrington at the U.S. Naval Observatory in Flagstaff, Arizona.
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Charon was discovered only about six miles from where Pluto itself was discovered at Lowell Observatory. They weren't even looking for satellites of Pluto – Christy, examining a series of grainy telescope images, trying to refine Pluto's orbit around the Sun.

Christy and others tell the story of this amazing scientific find, which fueled Pluto’s transformation from a telescopic dot into an actual planetary system – and a source of many discoveries to come.

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