In this Research Spotlight episode, Prof. Sarah Wengryniuk joins us to talk about selective dearomatization of phenols using hypervalent iodine reagents. This episode has been made possible through a collaboration with Thieme Chemistry (Twitter: @thiemechemistry) and is made in recognition of Prof. Sarah Wengryniuk as a recipient of the Thieme Chemistry Journal Award.
Key reference:
Synlett, 2021, 32, 752.
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Other references (in order of appearance):
For recent review on aerobic Cu-catalysis approaches see: Synlett, 2015, 26, 2731.
Magdziak, D. et. al. Org. Lett., 2002, 4, 285.
For reviews on I(V) reagents see: J. Org. Chem. 2011, 76, 1185.; Tetradedron 2010, 7659.; ACIE, 2011, 50, 1524.
Kaur, et. al. Org. Biomol. Chem., 2020, 18, 1117.
Seminal report from Pettus: Org. Lett., 2002, 4, 285.
For reviews on I(V) reagents see: J. Org. Chem. 2011, 76, 1185.; Tetradedron 2010, 7659.; ACIE, 2011, 50, 1524.
Zhdankin, V. V. et al. Tetradedron Lett. 2002, 43, 5735.
Seminal report on N-HVI see: Weiss, R. et. al. Angew. Chem. Int. Ed. 1994, 33, 891.; For a useful review on N-HVI see: Corbo, R. et al. Coord. Chem. Rev. 2018, 375, 69.
Xiao, X. et. al. J. Org. Chem. 2021, 86, 6566.
Seminal report on N-ligated I(V) reagents : Zhdankin, V. V. et al. Tetradedron Lett. 2002, 43, 5735.
Xiao, X. et al., Angew. Chem. Int. Ed. 2019, 58, 16181.
J. Org. Chem. 2021, 86, 12237.
