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In chemistry, sigma bonds (σ bonds) are the strongest type of covalent chemical bond.[1] They are formed by head-on overlapping between atomic orbitals. Sigma bonding is most clearly defined for diatomic moleculesusing the language and tools of symmetry groups. In this formal approach, a σ-bond is symmetrical with respect to rotation about the bond axis. By this definition, common forms of sigma bonds are s+s, pz+pz, s+pz and dz2+dz2 (where z is defined as the axis of the bond).[2] Quantum theory also indicates that molecular orbitals (MO) of identical symmetry actually mix. As a practical consequence of this mixing of diatomic molecules, thewavefunctions s+s and pz+pz molecular orbitals become blended. The extent of this mixing (or blending) depends on the relative energies of the like-symmetry MO's

In chemistry, pi bonds (π bonds) are covalent chemical bonds where two lobes of one involved atomic orbital overlap two lobes of the other involved atomic orbital. Each of these atomic orbitals is zero at a shared nodal plane, passing through the two bonded nuclei. The same plane is also a nodal plane for the molecular orbital of the pi bond.

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