This is from Season 10, Episode 9. After Dean, Sam and Castiel saves the girl (Castiel's vessel/Jimmy's daughter
) Dean get's caught my some mob-dealers in the house.He get's reflections of the mark and says "Boys, you don't wanna do this" He then get's slapped and Dean becomes a demon again for a short periode of time. Sam then comes in and sees Dean like that and question's him.
This footage is record by me!
But I DO NOT own the footage
LISTEN CLOSELY TO DEAN IN THE BACKGROUND WHEN SAM IS IN THE CAR!
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