At the beginning of the episode, Chandler helps Joey rehearse for an audition. The rehearsal calls for Joey to smoke a cigarette, and as Joey is not a smoker and coughs after taking a drag, Chandler, who used to smoke, demonstrates the "proper" smoking technique to Joey. But as he begins to take a few drags, he becomes addicted and picks up his old habit again. Throughout the episode, the gang try to persuade him to quit, which irritates him greatly. He defends himself by saying it is just a flaw of his, and claims that they are being hypocritical, as they all have their own irritating habits (e.g. Monica's snorting, Joey's knuckle-cracking, Phoebe chewing her hair, Ross's over pronouncing of every word).
Chandler tries using patches to quit smoking, but gives up at the end of the episode, and announces he is getting cigarettes. Phoebe then offers him the $7,000 in return for not smoking again; Chandler gladly obliges.
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